To be a MLB Stringer you have to pass their scorekeeping test and you can also get paid to keep minor league score for Baseball Information Systems, for which you have to pass their test.
I've run across a couple of different sites that talked about something like a scorekeeping certification but they all seem to have died.
Andrew Wirkmaa (wirkmaa.com) is working on a comprehensive scorekeeper's manual but no idea when it'll come to fruition.