Let's dont start this subject again. A stopwatch may be slightly useful for timing 50mph pre-teen throws, and nothing above.
To even approach accuracy you'd probably have to measure and average 20 fastballs. 1/10 second error is huge. And coming that close will require a good watch and lightening fast reflexes.
An 80mph fastball takes less than 0.6 second to reach the plate.
There are better ways to estimate speed:
If the kid is really throwing 90 for example, just ask one of the 10 scouts with guns how fast he's throwing.
80 looks pretty good, about the same speed as the other starters.
70 is noticeably slow at HS varsity.