NC -- I'm with you on the explosiveness and the intent to throw hard. In my mind and experience, this is part mental, and part physical.
The mental is the "intent" as you say. You have to want to throw hard (or hit hard) ... while hitting the right spot. On the physical side, I have long believed this is best achieved through simple, coordinated, fluid, movements -- executed in optimum alignment -- long before I ever heard of a kinetic chain
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Finesse in movement, delivered with power and authority.
I learned this more from my Rugby career than my Baseball career. It was on the Rugby pitch that I learned how to best deliver power from your toes to your nose, for the purpose of moving (or stopping) things intent on going the other direction. Wasted, or un-synchronized movements leak energy/power, and can leave parts vulnerable to breaking. Unfortunately, delivering power with absolute efficiency can also lead to breaking things
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When Coach House challenged my son to get to footstrike within 1 seocnd of first forward movement, he became more explosive. At the same time, he emphasized keeping the mechanics fluid. The result has been repeatable efficiency & effectiveness.
It is funny that you make the connection between hitting & pitching. We were just having this conversation yesterday with my son's hitting instructor (MLB Scout & Rookie Ball Manager); that a hitter's loading & firing is similar to a pitcher's delayed hip and shoulder rotation. Both movements "wind the rubber band".
It also ties into the work the NPA has done with the Titlist Performance Institue. Rotational power, through an efficient motion, accentuated by proper tempo, delivers optimum power to and through the ball ... in both throwing and hitting.
Here's another stray thought ... my son is doing some strength and conditioning work with a football & track coach who is working him with some defensive backs. They need to develop the same powerful legs and, strong flexible core that Pitchers and Hitters require. Think about it ...
Thanks to all for the great thoughts.